MATHESON GAS PRODUCTS -- PROPANE -- 6830-00-261-7445
===================== Product Identification ===================== Product ID:PROPANE MSDS Date:06/25/1990 FSC:6830 NIIN:00-261-7445 === Responsible Party === Company Name:MATHESON GAS PRODUCTS Address:30 SEAFIEW DRIVE City:SEACAUCUS State:NJ ZIP:07096 Country:US Info Phone Num:201-867-4100/CHEMTREC 800-424-9300 Emergency Phone Num:201-867-4100/CHEMTREC 800-424-9300 CAGE:0FB11 === Contractor Identification === Company Name:MATHESON GAS PRODUCTS Address:30 SEAFIEW DRIVE Box:City:SEACAUCUS State:NJ ZIP:07096 Country:US Phone:201-867-4100, CHEMTREC 800-424-9300 CAGE:0FB11 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT; 9293 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:LIQUID MAY CAUSE FROSTIBITE, BLISTERS, BLURR VISION TO SKIN/EYES. NARCOTIC/SIMPLE ASPHYXIANT. HIGH CONCENTRATIONS MAY CAUSE DIZZINESS/DISORIENTATION/EXCITATION/HEADACHE/VOMITIMG/UNCONSCIOUSNE SS DUE TO ASPHYXIATION. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:ABOVE 100,000 PPM; SYMPTOMS OF EXPOSURE MAY INCLUDE DIZZINESS, STUPOR, AND UNCONSCIOUSNESS. ACGIH CLASSIFIES PROPANE AS AN ASPHYXIANT. FROSTBITE/BLISTERS/REDNESS/BLURRED VISION/PAIN. Medical Cond Aggravated by Exposure:NONE KNOWN ======================= First Aid Measures ======================= First Aid:EYES:WASH W/LAG AMTS WATER FOR 15-20MIN. CALL DOCTOR. SKIN:FROSTBITE:WARM AREA W/LUKEWARM WATER OR WRAP IN BLANKETS.EXERCISE AFFECTED PART FOR CIRCULATION. INHAL:REMOVE PERSON TO FRESH AIR. IF NOT BRE ATHING, GIVE CPR & OXYGEN. KEEP WARM & @REST. CALL DOCTOR. INGEST:TREAT LIPS/MOUTH/MUCOUS MEMBRANES FOR FROSTBITE. CALL DOCTOR. ===================== Fire Fighting Measures ===================== Flash Point:=-105.C, -157.F Autoignition Temp:=450.C, 842.F Lower Limits:9.5% Upper Limits:2.1% Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, OR HALON. LG FIRES USE WATER SPRAY OR FOG. Fire Fighting Procedures:MOVE CONTAINER FROM FIRE AREA IF POSSIBLE.COOL FIRE-EXPOSED CONTAINERS W/WATER.W/DRAW IF RISING SOUND FROM VENTING SAFETY DEVICE OR DISCOLORATION OF TANK. Unusual Fire/Explosion Hazard:DANGEROUS FIRE/EXPLO HAZ WHEN EXPOSED TO HEAT/FLAME.VAPORS HEAVIER THAN AIR;MAY TRAVEL CONSIDERABLE DISTANCE. SEE SUPPLEMENTAL DATA. ================== Accidental Release Measures ================== Spill Release Procedures:STOP LEAK IF POSSIBLE. ELIMINATE ALL SOURCES OF IGNITION. VENTILATE AREA. REDUCE VAPORS W/WATER SPRAY. EVACUATE ALL PERSONNEL. PROPANE IS HEAVIER THAN AIR & CAN SETTLE INTO LOW AREAS. AVOID TOUCHING G AS. Neutralizing Agent:NOT APPLICABLE. ====================== Handling and Storage ====================== Handling and Storage Precautions:DO NOT DROP CYLINDER. STORE IN CONTAINERS MEETING BONDING & GROUNDING GUIDELINES SPECIFIED IN NFPA 77-1983, RECOMMENDED PRACT ON STATIC ELECTIRICITY. Other Precautions:STORAGE TEMPERATURE SHOULD BE KEPT BELOW 125F. CYLINDERS MUST NOT BE RECHARGED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SELF-CONTAINED BREATHING APPARATUS WHERE THE CONCENTRATION OF PROPANE WOULD REDUCE OXYGEN LEVEL BELOW 18% IN INHALED AIR. Ventilation:USE EXPLOSION PROOF VENTILATION EQUIPMENT. Protective Gloves:INSULATED LEATHER GLOVES AS REQUIRED. Eye Protection:SAFETY GLASSES, GOGGLES OR FACE SHIELD Other Protective Equipment:PROTECTIVE CLOTHING FOR MINIMUM SKIN CONTACT. NONE NORMALLY REQUIRED. EYE WASH FOUNTAIN & QUICK DRENCH SHOWER. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. USE PROPER CARE WHEN HANDLING AND STORING CYLINDERS. Supplemental Safety and Health LOW ELECTROCONDUCTIVITY OF PROPANE, FLOW OR AGITATION MAY GENERATE ELECTROSTATIC CHARGES RESULTING IN SPARKS W/POSSIBLE IGNITION. REFER TO CGA BULLETIN SB-2 "OXYGEN DEFICIENT ATMOSPHERES". STIMULANTS SUCH AS EPINEPHRINE MAY INDUCE VENTRICULAR FIBRILLATION. ================== Physical/Chemical Properties ================== HCC:G2 Boiling Pt:=-42.2C, -44.F Melt/Freeze Pt:=-190.C, -310.F Vapor Pres:6536 Vapor Density:1.55 Spec Gravity:0.5853 @-45C Solubility in Water:VERY SLIGHTTLY Appearance and Odor:COLORLESS GAS WITH A CHARACTERISTIC NATURAL GAS ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES BARIUM PEROXIDE, CHLORINE DIOXIDE, PLASTICS, RUBBER, COATINGS, STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES OF IGNITION. CYLINER UNDER PRESSURE-MAY EXPLODE. VAPORS MAY BE EXPLOSIVE. Hazardous Decomposition Products:CARBON MONOXIDE, TOXIC OXIDES OF CARBON. ==================== Disposal Considerations ==================== Waste Disposal Methods:MOVE LEAKY CYLINDER TO OUTDOORS OR VENTILATED HOOD. ALLOW GAS TO DISCHARGE AT MODERATE RATE. DISPOSE IAW FED/STATE/LOCALREGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.