CITGO PETROLEUM CORP -- ANTIFREEZE AND COOLANT, 0161  -- 6850-00-664-1403
<pre>=====================  Product Identification  =====================

Product ID:ANTIFREEZE AND COOLANT, 0161
MSDS Date:02/12/1996
FSC:6850
NIIN:00-664-1403
=== Responsible Party ===
Company Name:CITGO PETROLEUM CORP
Box:3758
City:TULSA
State:OK
ZIP:74102
Country:US
Info Phone Num:918-495-5933
Emergency Phone Num:918-495-4700; 800-424-9300
CAGE:1JW40
=== Contractor Identification ===
Company Name:CITGO PETROLEUM CORP
Address:OFF HWY 108
Box:3758
City:LAKE CHARLES
State:LA
ZIP:70602
Country:US
Phone:918-561-5165
CAGE:1JW40
Company Name:CITIES SERVICE RESEARCH AND DEVELOPMENT
Address:110 W. 7TH
Box:300
City:TULSA
State:OK
ZIP:74102
Country:US
CAGE:73589

=============  Composition/Information on Ingredients  =============

Ingred Name:ETHYLENE GLYCOL (SARA 313) (CERCLA)
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: 90-95%
OSHA PEL:N/K 
ACGIH TLV:50 PPM, VAPOR, C
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB

Ingred Name:DIETHYLENE GLYCOL
CAS:111-46-6
RTECS #:ID5950000
Fraction by Wt: 0-5%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:POTASSIUM PHOSPHATE; DIBASIC; (DIPOTASSIUM PHOSPHATE)
CAS:7758-11-4
Fraction by Wt: <5%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:ADDITIVES AND OTHER INGREDIENTS; (ADDITIVES AND DYES)
Fraction by Wt: <5%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:SUPDAT:MAY BE EXPECTED 24-72 HRS AFTER INGEST.
    INJECTION:SUBCUTANEOUS/INTRAMUSC INJECTION MAY CAUSE IRRIT,
    INFLAM(ING 6)
RTECS #:9999999ZZ

Ingred Name:ING 5: & SWELL. CHRONIC: INHAL:ETHYLENE GLYCOL HAS PRDCED
    BIRTH DEFECTS IN LAB ANIMALS. LITTLE INFO IS AVAIL (ING 7)
RTECS #:9999999ZZ

Ingred Name:ING 6:ON EFTS OF CHRONIC INHAL EXPOS TO ETHYLENE GLYCOL IN
    HUMANS. RPTS OF NERVOUS SYS DISORDERS IN RUSSIAN (ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7:WORKERS EXPOS TO 49PPM OF ETHYLENE GLYCOL OVER
    EXTENDED TIME. SKIN:PRDCES IRRIT W/RPTD/PRLNGD EXPOS. MAY (ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8:BE ABSORBED. EYE:VAPS PRDCED SEV IRRIT IN RABBITS &
    CORNEAL DMG IN RATS. INGEST:STUDIES OF LAB ANIMALS (ING 10)
RTECS #:9999999ZZ

Ingred Name:ING 9:RSLTD IN KIDNEY DMG, OFTEN W/DEPOSITS OF CALCIUM
    OXALATE. FOR EX, KIDNEY DMG WAS PRDCED IN MONKEYS GIVEN (ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 10: ETHYLENE GLYCOL IN	DRINKING WATER. CALCIUM OXALATE
    CRYSTALS WERE ALSO FOUND IN THE BRAIN.
RTECS #:9999999ZZ

Ingred Name:FIRST AID:PRDCED ACCUM OF GLYCOLATE & GLYOXALATE WHICH FORM
    LACTATE & RSLTS IN METABOLIC ACIDOSIS, RENAL & HEART(ING 13)
RTECS #:9999999ZZ

Ingred Name:ING 12:FAILURE & PULM EDEMA. RPTS OF KIDNEY INSUFFICIENCY
    AFTER 2-3 DAYS OF INGEST. KIDNEY FAILURE MAY BE CAUSED(ING 14)
RTECS #:9999999ZZ

Ingred Name:ING 13: BY ACCUM OF CALCIUM OXALATE CRYSTALS. CRYSTALLURIA
    CAN BE EARLY SIGN OF ETHYLENE GLYCOL POISONING.
RTECS #:9999999ZZ

Ingred Name:SPILL PROC: USE OF PERSONAL PROT EQUIP. CNTN SPILL IN
    TEMPORARY DIKES TO AVOID PROD MIGRATION & TO ASSIST IN (ING 16)
RTECS #:9999999ZZ

Ingred Name:ING 15: RECOVERY. DO NOT ALLOW MATL TO ESCAPE INTO SEWERS,
    GROUND WATER, DRAINAGE DITCHES/SURF WATERS. REPORT (ING 17)
RTECS #:9999999ZZ

Ingred Name:ING 16: RELEASES AS REQD BY LAW TO APPROP STATE & FEDERAL
    AUTHORITIES.
RTECS #:9999999ZZ

Ingred Name:HNDLG/STOR PRECS: FED, STATE & LOCAL AUTHS BEFORE REUSING,
    RECONDITIONING, RECLAIMING, RECYCLING OR DISPOSING (ING 19)
RTECS #:9999999ZZ

Ingred Name:ING 18: OF EMPTY CNTNRS &/OR WASTE RESIDUAL OF THIS
    PRODUCT.
RTECS #:9999999ZZ

Ingred Name:OTHER PRECS: REMOVE CONTAMD CLTHG. LAUNDER BEFORE REUSE.
    WASH EXPOSED SKIN THOROUGHLY W/SOAP & WATER. KEEP (ING 21)
RTECS #:9999999ZZ

Ingred Name:ING 20: UNNECESSARY PERSONS FROM HAZARD AREA.
RTECS #:9999999ZZ

Ingred Name:VENT: LEVELS AS EVALUATED BY DESIGNATED PERSONNEL.
RTECS #:9999999ZZ

Ingred Name:PROT GLOVES: BUTYL RUBBER, NATURAL RUBBER, NEOPRENE,
    POLYETHYLENE, POLYVINYL ALCOHOL OR NITRILE RUBBER SHOULD BE USED.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL:SEV RESP IRRITANT. IN GEN
    EFTS BECOME NOTICEABLE W/AIRBORNE CONC OF APPROX 60PPM. COUGH &
    BURNING SENSATION IN TRACHEA ARE SYMPS OF EXPOS ABOVE 80PPM. CNS
    DEPRESSANT; SYMPS INCL HDCH, WEA K, NAUS, DIZZ, LOSS OF JUDGMENT &
    COORD. COMA & DEATH AT HIGH CONCS ARE POSS. SKIN:IRRITANT & MAY BE
    (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:ABSORBED THRU SKIN. EYE:MAY RSLT IN
    IMMED DISCOMFORT W/MILD TEMPORARY CONJ INFLAM; PERM DMG NOT ANTIC.
    INGEST:PREDOMINANT HAZ IS ASSOC W/INGEST OF LG QTYS AT SINGLE TIME.
    DURING FIRST 12 HRS,  MAY EXPERIENCE CNS EFTS SUCH AS HDCH, WEAK,
    NAUS, DIZZ, LOSS OF JUDGMENT & COORD. IN MILD CASES, APPEARS DRUNK
    (SUPDAT)
Medical Cond Aggravated by Exposure:PREEXISTING KIDNEY DISEASE.

=======================  First Aid Measures  =======================

First Aid:INHAL:MOVE TO FRESH AIR. ADMIN CPR & O*2 AS NEC. SEEK MED
    ATTN IMMED. SKIN: RINSE EXPOS AREA W/WATER. REMOVE CONTAMD CLTHG;
    WASH BEFORE REUSE. SEEK MED ATTN IF IRRIT IS SERIOUS OR PERSISTS.
    EYES:IMMED	WASH W/LG AMTS OF WATER FOR @ LST 15 MIN, OCCASNLY
    LIFTING LIDS. SEEK MED ATTN IMMED. INGEST:GIVE 2 GLASSES OF WATER &
    INDUCE VOMIT. SEEK MED ATTN IMMED. NOTE TO MD:INGEST OF ETHYLENE
    GLYCOL (ING 12)

=====================  Fire Fighting Measures  =====================

Flash Point:250F,121C
Lower Limits:3.2%
Extinguishing Media:FOR SMALL FIRES USE DRY CHEMICAL OR CARBON DIOXIDE.
    FOR LARGE FIRES USE WATER SPRAY, FOG OR FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
    EQUIPMENT . USE WATER SPRAY OR FOG NOZZLE TO KEEP CONTAINERS COOL.
    VENTILATE ENCLOSED AREAS BEFORE ENTERING.
Unusual Fire/Explosion Hazard:ETHYLENE GLYCOL PRESENTS A MODERATE
    EXPLOSION HAZARD WHEN EXPOSED TO FLAME AND AIR.

==================  Accidental Release Measures  ==================

Spill Release Procedures:REMOVE ALL HEAT & IGNIT SOURCES. ISOLATE AREA
    & RESTRIC ACCESS TO PERS WEARING PROT EQUIP. SM SPILL:ABSORB MATL
    W/NON-COMBUST ABSORB. PLACE INTO CNTNRS FOR DISP. LG
    SPILLS:EVACUATE AREA. ADEQUATELY VE NT & DETERM POTNTL EXPOS
    CNDTNS; MAY REQ (ING 15)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:DO NOT APPLY HIGH HEAT/FLAME TO CNTNR.
    PROD MAY CAUSE SLIPPERY CNDNTS ON WALKING SURFS IF SPILLED.
    PRACTICE REASONABLE CARE. CONSULT APPROP (ING 18)
Other Precautions:DURING REPAIR & MAINT OF CONTAMD EQUIP:DRAIN & PURGE
    EQUIP AS NEC TO REMOVE MATL RESIDUES. USE IMPERVIOUS GLOVES (BUTYL
    RUB, NATRL RUB, NEOPRENE OR NITRILE RUB) & PROT WORK CLTHG IF
    DIRECT CNTCT IS AN TIC. ELIM HEAT & IGNIT SOURCES. (ING 20)

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:ONLY NIOSH APPRVD ORGANIC VAPOR & DUST/MIST
    RESPIRATORS SHOULD BE USED. FOR AIRBONE CONCS AT OR ABOVE 500 PPM,
    SUPPLIED-AIR RESPIRATOR OR SCBA W/FULL FACE MASK MUST BE USED.
    RESPIRATORY PROT SHOULD BE	SELECTED ON BASIS OF MAX ANTIC CONC.
Ventilation:IN CONFINED SPACE, MECH VENT MAY BE REQD TO KEEP LEVELS OF
    CERTAIN COMPONENTS BELOW APPLIC WORKPLACE EXPOSURE (ING 22)
Protective Gloves:WORK GLOVES CONSTRUCTED OF (ING 23)
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . FULL
    BODY PROTECTIVE WORK CLTHG. LAUNDER CONTAMD WORK CLOTHES BEFORE
    REUSE.
Work Hygienic Practices:GARMENTS CONTAMINATED W/PRODUCT SHOULD BE
    CHANGED. SHOWER W/SOAP & WATER TO REMOVE ANY RESIDUES FROM SKIN.
Supplemental Safety and Health
SPEC GRAV: 1.11-1.14 (H*2O=1). PH (50% BY VOL): 10-11. CNDTNS TO AVOID:
    PHOSPHORUS PENTASULFIDE. EFTS OF OVEREXP:W/OUT BRTH OF ALCOHOL. IN
    MORE SEV CASES, CONVLS & COMA. FOLLOWED BY CARDIOPULM SYMPS I NCL
    MILD HYPERTENSION, ABNORM FAST HEARTBEAT & BRTHG RATE. KIDNEY
    COMPLICATIONS INCL SLOW/NO URINE PRODUCTION, (ING 5)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:259F,126C
Melt/Freeze Pt:M.P/F.P Text:-35F,-37C
Vapor Pres:0.05
Vapor Density:2.14
Spec Gravity:SUPDAT
pH:SUPDAT
Evaporation Rate &amp; Reference:<0.002 (BUTYL ACETATE=1)
Solubility in Water:SOLUBLE
Appearance and Odor:BLUE-GREEN LIQUID; ODORLESS.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS. ETHYLENE GLYCOL IGNITES ON CNTCT W/CHROMIUM TRIOXIDE,
    POTASSIUM PERMANGANATE OR SODIUM PEROXIDE.
Stability Condition to Avoid:ETHYLENE GLYCOL CAN REACT VIOLENTLY
    W/CHLORSULFONIC ACID, OLEUM, SULFURIC ACID, PERCHLORIC ACID, NITRIC
    ACID & (SUPDAT)
Hazardous Decomposition Products:WHEN HEATED TO DECOMP TEMPS, THIS MATL
    EMITS CARBON MONOXIDE, CARBON DIOXIDE & IRRITATING & ACRID FUMES.

====================  Disposal Considerations  ====================

Waste Disposal Methods:TREATMENT, STORAGE, TRANSPORTATION & DISPOSAL
    MUST BE IN ACCORDANCE W/APPLICABLE FEDERAL, STATE AND LOCAL
    REGULATIONS. CONTACT RCRA/SUPERFUND HOTLINE AT 1-800-424-9346 OR
    REGIONAL UP EPA OFFICE FOR GU IDANCE CONCERNING CASE SPECIFIC
    DISPOSAL ISSUES.

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