FISHER SCIENTIFIC CHEMICAL -- SODIUM BICARBONATE, S233 -- 6810-00-241-1143
===================== Product Identification ===================== Product ID:SODIUM BICARBONATE, S233 MSDS Date:06/30/1994 FSC:6810 NIIN:00-241-1143 === Responsible Party === Company Name:FISHER SCIENTIFIC CHEMICAL Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:800-424-9300 (CHEMTREC) CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM BICARBONATE (1:1) CAS:144-55-8 RTECS #:VZ0950000 Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUP DAT: W/INCR IN PLASMA CARBON DIOXIDE & PH & 1 CASE OF ALBUMINURIA & HEMATURIA. INCRD ACIDITY, SODIUM CONTENT (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: AND VOLUME OF URINE AND CRYSTALLURIA HAVE BEEN REPORTED IN RATS. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: LIFTING UPPER & LOWER LIDS, UNTIL NO EVIDENCE OF CHEM REMAINS (AT LEAST 15-20 MIN). GET MED ATTN (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: IMMED. INGEST: IF VOMITING OCCURS, KEEP HEAD LOWER THAN HIPS TO PREVENT ASPIR. TREAT SYMPTOMATICALLY & (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: SUPPORTIVELY. GET MED ATTN IF NEEDED. ANTIDOTE: NO SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY & SUPPORTIVELY. RTECS #:9999999ZZ Ingred Name:RESP PROT: MUST BE BASED ON SPECIFIC OPERATION, MUST NOT EXCEED THE WORKING LIMITS OF RESP & MUST BE APPRVD BY (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: NIOSH. ANY DUST & MIST RESP. ANY AIR-PURIFYING RESP W/HIGH-EFFICIENCY PARTICULATE FILTER. ANY POWERED (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: AIR-PURIFYING RESP W/DUST & MIST FILTER. ANY POWERED AIR-PURIFYING RESP W/HIGH-EFFICIENCY PARTICULATE (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: FILTER. ANY TYPE 'C' SUPPLIED-AIR RESP OPERATED IN PRESS-DEMAND/OTHER POS PRESS/CONTINUOUS-FLOW MODE. (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: ANY SCBA. FOR FIREFIGHTING & OTHER IMMED DANGEROUS TO LIFE/HLTH CNDTNS: ANY SCBA THAT HAS FULL FACEPIECE(ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: & IS OPERATED IN PRESS-DEMAND/OTHER POS-PRESS MODE. ANY SUPPLIED-AIR RESP THAT HAS A FULL FACEPIECE & (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: IS OPERATED IN A PRESS-DEMAND/OTHER POS-PRESS MODE IN COMBINATION W/AN AUXILIARY SCBA OPERATED IN (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13: PRESSURE-DEMAND OR OTHER POSITIVE-PRESSURE MODE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT): 4220 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: MAY CAUSE SORE THROAT & COUGHING. DUST MAY IRRITATE NOSE, THROAT & LUNGS. SKIN: PRLNG CONT MAY CAUSE IRRIT. EYES: DIRECT CONT W/EYES MAY CAUSE IRRIT W/REDNESS & PAIN. INGEST: MAY CAUSE I RRIT OF MOUTH, ESOPHAGUS, & STOM. IN STOM, CARBON DIOXIDE GAS MAY BE RELEASED, CAUSING DISTENSION, (EFTS OF OVEREPOSURE) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: BELCHING, & POSS RUPTURE OF STOM. DOSES GREATER THAN 5 MG/KG MAY CAUSE ALKALOSIS & EDEMA. HYPOCALCEMIC TETANY ACCOMPANIED BY HYPOGLYCEMIA, CARPOPEDAL SPASM & CARDIOPULM ARREST HAVE ALSO BEEN REPORTED. CHRONIC: SKIN: HUMANS EXPOSED INTERMITTENTLY FOR 3 DAYS EXPERIENCED ONLY MILD IRRIT. ALKALOSIS HAS (SUP DAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE FROM EXPOS AREA TO FRESH AIR IMMED. PERFORM ARTF RESP IF NEC. KEEP PERS WARM & QUIET & AT REST. TREAT SYMPTOMATICALLY & SUPPROTIVELY. GET MED ATTN IMMED. SKIN: REMOVE CONTAM CLTHG & SHOE S IMMED. WASH W/SOAP/MILD DETERGENT & LGE AMTS OF WATER UNTIL NO EVIDENCE OF CHEM REMAINS (AT LEAST 15-20 MIN). GET MED ATTN IMMED. EYES: WASH IMMED W/LGE AMTS OF WATER/NORM SALINE, OCCAS (ING 4) ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR FOAM. FOR LARGER FIRES, USE WATER SPRAY, FOG OR ALCOHOL FOAM. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROT EQUIPMENT . NO ACUTE HAZARD. MOVE CONTAINER FROM FIRE AREA IF POSSIBLE. AVOID BREATHING VAPORS/DUSTS; KEEP UPWIND. Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP AND PLACE IN SUITABLE CLEAN, DRY CONTAINERS FOR RECLAMATION OR LATER DISPOSAL. DO NOT FLUSH SPILLED MATERIAL INTO SEWER. KEEP UNNECESSARY PEOPLE AWAY. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:AVOID REPEATED OR PROLONGED CONTACT WITH THIS SUBSTANCE. STORE AWAY FROM INCOMPATIBLE SUBSTANCES. Other Precautions:STORE IN TIGHTLY CLOSED CONTAINERS; PREVENT EXPOSURE TO MOISTURE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:THE FOLLOWING RESPS ARE REC BASED ON INFO FOUND IN PHYSICAL DATA, TOX & HLTH EFTS SECTIONS. THEY ARE RANKED IN ORDER FROM MIN TO MAX RESP PROT. THE SPECIFIC RESP SELECTED MUST BE BASED ON CONTAM LEVEL S FOUND IN WORK PLACE, (ING 7) Ventilation:PROVIDE LOCAL EXHAUST VENTILTION SYSTEM. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . PROTECTIVE CLOTHING NOT REQUIRED. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health PH: 8.3 @ 0.84% SOLN. MATLS TO AVOID: MONOAMMONIUM PHOSPHATE: SELF-PROPAGATING RXN W/RAPID BUILD-UP OF PRESS. SODIUM-POTASSIUM ALLOY: VIOLENT RXN. EFTS OF OVEREXP: BEEN REPORTED FROM TOPICAL APPLICATI ON. INGEST: INGEST OF UP TO 140 G/DAY FOR 3 WKS CAUSED CONSIDERABLE WT GAIN DUE TO FLUID RETENTION, ALKALOSIS (ING 2) ================== Physical/Chemical Properties ================== Spec Gravity:2.159 pH:SUPDAT Solubility in Water:10% Appearance and Odor:ODORLESS, WHITE POWDER OR GRANULES WITH A COOLING, SLIGHTLY ALKALINE TASTE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS: MAY REACT VIOLENTLY AND RELEASE CARBON DIOXIDE. 2-FURALDEHYDE: POSSIBLE IGNITION HAZARD. (SUP DAT) Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND PRESSURES. Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE TOXIC OXIDES OF CARBON. ==================== Disposal Considerations ==================== Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN STORING OR DISPOSING OF THIS SUBSTANCE. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.