FISHER SCIENTIFIC CHEMICAL -- AMMONIUM CHLORIDE, A661 -- 6810-00-312-7114
===================== Product Identification ===================== Product ID:AMMONIUM CHLORIDE, A661 MSDS Date:08/28/1991 FSC:6810 NIIN:00-312-7114 === Responsible Party === Company Name:FISHER SCIENTIFIC CHEMICAL Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7100;800-424-9300(CHEMTREC) CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:AMMONIUM CHLORIDE (CERCLA) LD50 (ORAL RAT): 1650 MG/KG CAS:12125-02-9 RTECS #:BP4550000 Fraction by Wt: 100% OSHA PEL:10 MG/M3 ACGIH TLV:10 MG/M3 FUME EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SUP DAT: HYPOPROTEINEMIA, DEMINERALIZATION OF BONEY STRUCTURES & COMA. RABBITS W/DAMAGED LIVERS, & ADRENALS (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: REMOVED, WERE FED AMMONIUM CHLORIDE FOR 120 DAYS, RSLTG IN PERM CHANGES IN ELECTRORETINOGRAM & (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: DEGENERATION OF GANGLION CELL LAYER OF RETINA. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: EVIDENCE OF CHEM REMAINS (APPROX 15-20 MIN). GET MED ATTN IMMED. INGEST: TREAT SYMPTOMATICALLY (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: & SUPPORTIVELY. GET MED ATTN IMMED. IF VOMIT OCCURS, KEEP HEAD LOWER THAN HIPS TO PVNT ASPIRATION. (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: ANTIDOTE: NO SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY AND SUPPORTIVELY. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 1. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: DUST MAY CAUSE IRRIT W/COUGHING, SORE THROAT & DFCLT BRTHG. LAB ANIMALS EXPOSED TO 50 MG/M3 FOR 6 HRS SHOWED NO SIGNS OF INTOXICATION, HOWEVER, POST MORTEM EXAMINATION SHOWED CONGESTION OF TRACHEA & BRONCH MUCOSA; LUNGS WERE DISTENDED & EMPHYSEMATOUS W/PETECHIAL HEMORRHAGING & HYPEREMIA. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: CHANGES WERE EVIDENT IN LIVER, SPLEEN & ADRENAL MEDULLA. SKIN: MAY CAUSE IRRIT. EYE: MAY CAUSE IRRIT W/REDNESS & PAIN. SOLNS <10% ARE GEN WELL TOLERATED. INGEST: MAY CAUSE IRRIT OF MOUTH & S TOM W/NAUS/VOMIT. LGE DOSES MAY CAUSE DIURESIS, SYSTEMIC ACIDOSIS & AMMONIA POISONING. CHRONIC: INHAL: NO DATA (SUP DAT) Medical Cond Aggravated by Exposure:PERSONS WITH IMPAIRED LIVER AND KIDNEY FUNCTION. INTERACTIONS WITH MEDICATIONS HAVE BEEN REPORTED. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR IMMED. IF BRTHG STOPPED, PERFORM ARTF RESP. KEEP WARM & AT REST. TREAT SYMPTOMATICALLY & SUPPORTIVELY. GET MED ATTN IMMED. SKIN: REMOVE CONTAM CLTHG & SHOES IMMED. WASH AFFE CTED AREA W/SOAP & WATER UNTIL NO EVIDENCE OF CHEM REMAINS (APPROX 15-20 MIN). GET MED ATTN IMMED. EYE: WASH IMMED W/LGE AMTS OF WATER/NORM SALINE, OCCAS LIFTING UPPER & LOWER LIDS, UNTIL NO (ING 5) ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR REGULAR FOAM. FOR LARGER FIRES, USE WATER SPRAY, FOG OR REGULAR FOAM. Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP . MOVE CONTR FROM FIRE AREA IF W/OUT RISK. DO NOT SCATTER SPILLED MATL W/HIGH-PRESS WATER STREAMS. (SUP DAT) Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP AND PLACE IN SUITABLE CLEAN, DRY CONTAINERS FOR RECLAMATION OR LATER DISPOSAL. DO NOT FLUSH SPILLED MATERIAL INTO SEWER. KEEP UNNECESSARY PEOPLE AWAY. REPORTABLE QUANTITY: 5000 POUNDS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:PROTECT AGAINST PHYSICAL DAMAGE. STORE IN DRY LOCATION. SEPARATE FROM ACIDS AND ALKALIS. SEPARATE FROM SILVER SALTS. Other Precautions:STORE IN A COOL, DRY PLACE; KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. STORE AWAY FROM INCOMPATIBLE SUBSTANCES. MAY BURN BUT DOES NOT IGNITE READILY. OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIO NS WHEN STORING THIS SUBSTANCE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SPECIFIC RESP MUST BE NIOSH APPRVD: ANY DUST & MIST RESP; ANY AIR-PURIFYING RESP W/HIGH-EFFICIENCY PARTICULATE FILTER; ANY POWERED AIR-PURIFYING W/DUST & MIST FILTER; ANY SCBA. FOR A COMPLETE LIST OF RESPS, CONT NEHC . Ventilation:PROVIDE LOCAL EXHAUST VENTILATION TO MEET PUBLISHED EXPOSURE LIMITS. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER . APPROP PROTECTIVE CLOTHING & EQUIPMENT TO PREVENT SKIN CONTACT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health APPEAR/ODOR: COOLING SALINE TASTE, HYGROSCOPIC W/TENDENCY TO CAKE. FIRE FIGHT PROC: DIKE FIRE-CTL WATER FOR LATER DISP. USE AGENTS SUITABLE FOR TYPE OF SURROUNDING FIRE. AVOID BRTHG HAZ VAPS, KEEP UPW IND. EFTS OF OVEREXP: AVAIL. SKIN: MAY CAUSE DERM. EYE: MAY CAUSE CONJ. INGEST: MAY CAUSE NAUS, VOMIT, ACIDOSIS, (ING 2) ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:644F,340C Vapor Pres:1 @ 160C Vapor Density:1.9 Spec Gravity:1.5 pH:5.0 Solubility in Water:28.3% @ 25C Appearance and Odor:ODORLESS, COLORLESS CRYSTALS/CRYSTALLINE MASSES/WHITE GRANULAR POWDER, (SUP DAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, STRONG OXIDIZERS, STRONG BASES, LEAD SALTS, METALS, & SILVER SALTS. FOR COMPLETE LIST, CONT NEHC . Stability Condition to Avoid:AVOID EXCESSIVE HEAT, SPARKS, OR OPEN FLAME. Hazardous Decomposition Products:MAY INCLUDE TOXIC FUMES OF AMMONIA, CHLORIDES, AND THE OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN DISPOSING OF THIS SUBSTANCE. FOR ASSISTANCE, CONTACT THE DISTRICT DIRECTOR OF THE ENVIRONMENTAL PROTECTION AGENCY. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.