SHERWIN-WILLIAMS CO THE -- QUIK-MARK INVERTED MARKING PAINTS-4 -- 8010-01-418-7646
===================== Product Identification ===================== Product ID:QUIK-MARK INVERTED MARKING PAINTS-4 MSDS Date:08/17/1998 FSC:8010 NIIN:01-418-7646 Status Code:A === Responsible Party === Company Name:SHERWIN-WILLIAMS CO THE Address:101 PROSPECT AVE NW City:CLEVELAND State:OH ZIP:44115-1042 Country:US Info Phone Num:216-566-2902/216-566-2917 Emergency Phone Num:216-566-2917 Preparer's Name:ERNEST CARTER Chemtrec Ind/Phone:(800)424-9300 CAGE:54636 === Contractor Identification === Company Name:SHERWIN-WILLIAMS CO THE Address:101 PROSPECT AVE NW Box:City:CLEVELAND State:OH ZIP:44115-1042 Country:US Phone:800-251-2486/216-566-2242 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 = Wt:13. OSHA PEL:1800 MG/M3;1000 PPM Ingred Name:BUTANE CAS:106-97-8 RTECS #:EJ4200000 = Wt:12. ACGIH TLV:1900 MG/M3;800 PPM Ingred Name:V.M.& P. NAPHTHA CAS:64742-89-8 Code:F = Wt:7. OSHA PEL:300 PPM OSHA STEL:400 PPM ACGIH TLV:3>0 Ingred Name:TOLUENE CAS:108-88-3 RTECS #:XS5250000 = Wt:10. OSHA PEL:SEE TABLE Z-2 ACGIH TLV:188 MG/M3;50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ACETONE CAS:67-64-1 RTECS #:AL3150000 = Wt:20. OSHA PEL:2400 MG/M3;1000 PPM ACGIH TLV:1780 MG/M3;750 PPM ACGIH STEL:2380 MG/M3;1000 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:CALCIUM CARBONATE = Wt:25. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Health Hazards Acute and Chronic:EXPOSURE MAY BE BY INHALATION AND/OR SKIN OR EYE CONTACT, DEPENDING ON CONDITIONS OF USE. TO MINIMIZE EXPOSURE, FOLLOW RECOMMENDATIONS FOR PROPER USE, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT. Effects of Overexposure:IRRITATION OF EYES, SKIN AND RESPIRATORY SYSTEM. MAY CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME OVEREXPOSURE MAY RESULT IN UNCONSCIOUSNESS AND POSSIBLY DEATH. HEADACHE, DIZZINESS, NAUSEA, AND LOSS OF CO ORDINATIONS OF EXCESSIVE EXPOSURE TO VAPORS OR SPRAY MISTS. REDNESS AND ITCHING OR BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN EXPOSURE. Medical Cond Aggravated by Exposure:NONE RECOGNIZED. ======================= First Aid Measures ======================= First Aid:IF INHALED: REMOVE FROM EXPOSURE. RESTORE BREATHING.KEEP WARM AND QUIET. IF ON SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER.REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE. IF IN EYE S: FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES.GET MEDICAL ATTENTION. IF SWALLOWED: DO NOT INDUCE VOMITING. GIVE SEVERAL GLASSES OF WATER. SEEK MEDICAL ATTENTION ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:<0 F Lower Limits:0.9% Upper Limits:27.0% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS SHOULD BE USED. WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. WATER MAY BE USED TO COOL CLOSED CO NTAINERS TO PREVENT PRESSURE BUILD UP AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE BUILD UP OF PRESSURE)WHEN EXPOSED TO EXTREME HEAT. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS AND OPEN FLAME. APPLICATION TO HOT SURFACES REQUIRES SPEC IAL PRECAUTIONS, DURING EMERGENCY CONDITIONS OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND RESOVE WITH INERT ABSORBENT ====================== Handling and Storage ====================== Handling and Storage Precautions:CONTENTS ARE EXTREMELY FLAMMABLE. KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME. VAPORS WILL ACCUMULATE READILY AND MAY IGNITE EXPLOSIVELY.DURING USE AND UNTIL ALL VAPORS ARE GONE . KEEP AREA VENTILATED .DO NOT SMOKE EXTINGUISH ALL FLAMES, PILOT LIGHTS, AND HEATERS KEEP OUT OF THE REACH OF CHILDREN. Other Precautions:INTENTIONAL MISUSE BY DELIBERATALY CONCENTRATING AND INHALING THE CONTENTS CAN BE HARMFUL OR FATAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW APPLICABLE LIMITS BY VENTILATION, WEAR A PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA FOR PROTECTION AGAINST MATERIALS IN SECTION II. Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE EXPOSURE TO MATERIALS IN SECTION II IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS. Protective Gloves:WEAR GLOVES WHICH ARE RECOMMENDED BY GLOVE SUPPLIER FOR PROTECTION Eye Protection:WEAR SAFETY SPECTACLES WITH UNPERFORATED SIDESHIELDS. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:<0-395 F Vapor Density:HEAVIER Spec Gravity:0.77-4.95 Evaporation Rate & Reference:FASTER THAN ETHER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THESE PRODUCTS MAY BE HAZARDOUS AS DEFINED UNDER THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE THE APPLICABLE EPA HAZARDOU S WASTE NUMBERS. DO NOT INCINERATE. DEPRESSURIZE CONTAINER. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS REGARDING POLLUTION. ===================== Regulatory Information ===================== Federal Regulatory Information:TSCA CERTIFICATION ALL CHEMICALS IN THESE CONTAINERS ARE LISTED, OR ARE EXEMPT FROM LISTING, ON THE TSCA INVENTORY. State Regulatory Information:CALIFORNIA PROPOSITION 65 WARNING: THESE PRODUCTS CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS AND OTHER REPRODUCTIVE HARM. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.